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int32
3,281
In the Bi 4f spectra shown in Figure (a), what is the approximate binding energy (in eV) of the highest-intensity peak observed in all samples?
approximately 158.8 eV
Caption: Figure 2: XPS spectra of pristine and degraded electrodes. Description: (a) Bi 4f, (b) O 1sand V 2pcore levels of pristine (black) and degraded at pH 6.8 (red) and pH 12.3 (blue) BiVO4samples compared with FTO (dashed grey).
0
3,282
In the FTO dashed spectrum, is the peak position shifted toward higher or lower binding energy compared to the O 1s main peak of the pH 12.3 sample?
Tending toward higher binding energy
Caption: Figure 2: XPS spectra of pristine and degraded electrodes. Description: (a) Bi 4f, (b) O 1sand V 2pcore levels of pristine (black) and degraded at pH 6.8 (red) and pH 12.3 (blue) BiVO4samples compared with FTO (dashed grey).
1
3,283
Which element’s photoelectron energy levels correspond to the two peaks at approximately 516 eV and 524 eV?
V 2p
Caption: Figure 2: XPS spectra of pristine and degraded electrodes. Description: (a) Bi 4f, (b) O 1sand V 2pcore levels of pristine (black) and degraded at pH 6.8 (red) and pH 12.3 (blue) BiVO4samples compared with FTO (dashed grey).
0
3,284
Comparing Figure a and Figure b, which spectrum shows more pronounced changes in both shape and relative intensity with varying pH?
Figure b
Caption: Figure 2: XPS spectra of pristine and degraded electrodes. Description: (a) Bi 4f, (b) O 1sand V 2pcore levels of pristine (black) and degraded at pH 6.8 (red) and pH 12.3 (blue) BiVO4samples compared with FTO (dashed grey).
1
3,285
Which sample is represented by the black solid line?
Pristine
Caption: Figure 2: XPS spectra of pristine and degraded electrodes. Description: (a) Bi 4f, (b) O 1sand V 2pcore levels of pristine (black) and degraded at pH 6.8 (red) and pH 12.3 (blue) BiVO4samples compared with FTO (dashed grey).
0
3,291
In the enlarged view of the H22 signal, what is the labeled chemical shift (ppm) for this signal?
6.40 ppm
Caption: Fig. 2: 1D1H NMR spectra of microgram amount of strychnine in gels. Description: c. 1D1H NMR spectrum of 10-μg strychnine acquired with 8192 scans in deuterated PMMA gel under maximum alignment condition. For clarity, expansions for some of the proton signals (H4, H22, H8, and H20a) are also shown.
0
3,292
Are the splitting patterns of H4 and H20a, in terms of peak shapes and counts, similar?
Yes
Caption: Fig. 2: 1D1H NMR spectra of microgram amount of strychnine in gels. Description: c. 1D1H NMR spectrum of 10-μg strychnine acquired with 8192 scans in deuterated PMMA gel under maximum alignment condition. For clarity, expansions for some of the proton signals (H4, H22, H8, and H20a) are also shown.
1
3,293
In the four enlarged signal plots arranged from left to right at the top, what is the name of the signal corresponding to the third plot?
H8
Caption: Fig. 2: 1D1H NMR spectra of microgram amount of strychnine in gels. Description: c. 1D1H NMR spectrum of 10-μg strychnine acquired with 8192 scans in deuterated PMMA gel under maximum alignment condition. For clarity, expansions for some of the proton signals (H4, H22, H8, and H20a) are also shown.
0
3,294
How many local magnified views are included in panel c?
4
Caption: Fig. 2: 1D1H NMR spectra of microgram amount of strychnine in gels. Description: c. 1D1H NMR spectrum of 10-μg strychnine acquired with 8192 scans in deuterated PMMA gel under maximum alignment condition. For clarity, expansions for some of the proton signals (H4, H22, H8, and H20a) are also shown.
1
3,295
Among the labeled signals, which one has the highest chemical shift value?
H4
Caption: Fig. 2: 1D1H NMR spectra of microgram amount of strychnine in gels. Description: c. 1D1H NMR spectrum of 10-μg strychnine acquired with 8192 scans in deuterated PMMA gel under maximum alignment condition. For clarity, expansions for some of the proton signals (H4, H22, H8, and H20a) are also shown.
0
3,296
Among curves I, II, III, and Shake up, which curve corresponds to the highest peak intensity?
Curve I
Caption: Fig. 3 Description: XPS Characterizations.aXPS spectrum of1for Cu 2p (brown) with three fitting peaksI–III(Cu(I): yellow; Cu(I)′: blue; Cu(II): green).bXPS of2for Cu 2p signal
0
3,297
Question: Among the three main fitted peaks (I, II, III), which one has the binding energy at the intermediate value? Answer: Peak II.
Peak II
Caption: Fig. 3 Description: XPS Characterizations.aXPS spectrum of1for Cu 2p (brown) with three fitting peaksI–III(Cu(I): yellow; Cu(I)′: blue; Cu(II): green).bXPS of2for Cu 2p signal
0
3,298
What is the signal peak located at approximately 943 eV called?
Shake up
Caption: Fig. 3 Description: XPS Characterizations.aXPS spectrum of1for Cu 2p (brown) with three fitting peaksI–III(Cu(I): yellow; Cu(I)′: blue; Cu(II): green).bXPS of2for Cu 2p signal
0
3,299
Which compound (Complex 1 or Complex 2) exhibits a higher main peak binding energy?
Complex 2
Caption: Fig. 3 Description: XPS Characterizations.aXPS spectrum of1for Cu 2p (brown) with three fitting peaksI–III(Cu(I): yellow; Cu(I)′: blue; Cu(II): green).bXPS of2for Cu 2p signal
1
3,300
What are the units of the horizontal axis and the vertical axis in panel b, respectively?
Horizontal axis: eV; Vertical axis: Counts/10^3 s
Caption: Fig. 3 Description: XPS Characterizations.aXPS spectrum of1for Cu 2p (brown) with three fitting peaksI–III(Cu(I): yellow; Cu(I)′: blue; Cu(II): green).bXPS of2for Cu 2p signal
0
3,301
In the powder XRD pattern shown in subfigure c, what is the approximate 2θ value corresponding to the labeled (100) diffraction peak?
≈25.3°
Caption: Fig. 2: Characterization of Mn-DTA MOF. Description: c. Powder XRD pattern of Mn-DTA (MnS, JCPDS No, 89-4089).
0
3,302
What is the Miller index of the crystal plane corresponding to the strongest diffraction peak in subfigure c?
It is (100)
Caption: Fig. 2: Characterization of Mn-DTA MOF. Description: c. Powder XRD pattern of Mn-DTA (MnS, JCPDS No, 89-4089).
0
3,303
In the 2θ range of 20° to 30°, how many diffraction peaks are indicated by the JCPDS reference pattern (the vertical lines below)?
five
Caption: Fig. 2: Characterization of Mn-DTA MOF. Description: c. Powder XRD pattern of Mn-DTA (MnS, JCPDS No, 89-4089).
1
3,304
Which of the diffraction peaks at (102) and (110) exhibits lower intensity?
(102) lower
Caption: Fig. 2: Characterization of Mn-DTA MOF. Description: c. Powder XRD pattern of Mn-DTA (MnS, JCPDS No, 89-4089).
1
3,305
What is the number of the standard card used as a reference?
JCPDS No.89-4089
Caption: Fig. 2: Characterization of Mn-DTA MOF. Description: c. Powder XRD pattern of Mn-DTA (MnS, JCPDS No, 89-4089).
0
3,306
What is the wavenumber at the center of the strong absorption peak located between 1500 cm⁻¹ and 1000 cm⁻¹?
1433 cm⁻¹
Caption: Fig. 5: The in situ dynamic evolution of carboxyl ligand. Description: b. In situ FTIR spectroscopy measurements on SU-NiFe-LDH(TA)@cp sample at different applied potentials.
0
3,307
How does the intensity of the absorption peak at 1608 cm⁻¹ change as the applied voltage increases from 0.0 V to 3.0 V?
Intensity enhancement
Caption: Fig. 5: The in situ dynamic evolution of carboxyl ligand. Description: b. In situ FTIR spectroscopy measurements on SU-NiFe-LDH(TA)@cp sample at different applied potentials.
1
3,308
Which three substances or states do the top three spectral curves (red, blue, and gray) correspond to, respectively?
TANa、TA、Membrane
Caption: Fig. 5: The in situ dynamic evolution of carboxyl ligand. Description: b. In situ FTIR spectroscopy measurements on SU-NiFe-LDH(TA)@cp sample at different applied potentials.
0
3,309
How many independent spectral curves are contained in the variable-voltage spectral sequence from 0.0 V to 3.0 V?
12
Caption: Fig. 5: The in situ dynamic evolution of carboxyl ligand. Description: b. In situ FTIR spectroscopy measurements on SU-NiFe-LDH(TA)@cp sample at different applied potentials.
1
3,310
In subfigure (b), is the horizontal axis (Wavenumber/cm⁻¹) continuous?
It is discontinuous, exhibiting a break at approximately 1750 cm⁻¹.
Caption: Fig. 5: The in situ dynamic evolution of carboxyl ligand. Description: b. In situ FTIR spectroscopy measurements on SU-NiFe-LDH(TA)@cp sample at different applied potentials.
0
3,311
In the upper subplot, what is the annotated mass-to-charge ratio (m/z) difference between adjacent main peaks?
607 Da, 608 Da, and 650 Da
Caption: Figure 1: Determination of the MPIase structure. Description: (b, top) MALDI–TOF MS spectrum of MPIase in the negative mode. Subdivided peaks differing in 42 mass units reflect variation ofO-acetyl groups. (Bottom) The MS/MS spectrum fromm/z608 in the positive mode contained fragment peaks comprising combinati...
0
3,312
What is the mass difference indicated in parentheses in the inset of the upper panel?
42 Da
Caption: Figure 1: Determination of the MPIase structure. Description: (b, top) MALDI–TOF MS spectrum of MPIase in the negative mode. Subdivided peaks differing in 42 mass units reflect variation ofO-acetyl groups. (Bottom) The MS/MS spectrum fromm/z608 in the positive mode contained fragment peaks comprising combinati...
0
3,313
In the lower subpanel, what are the masses of the fragments indicated by the bidirectional arrows?
218 Da、203 Da、187 Da
Caption: Figure 1: Determination of the MPIase structure. Description: (b, top) MALDI–TOF MS spectrum of MPIase in the negative mode. Subdivided peaks differing in 42 mass units reflect variation ofO-acetyl groups. (Bottom) The MS/MS spectrum fromm/z608 in the positive mode contained fragment peaks comprising combinati...
0
3,314
In the MS/MS spectrum below, what is the mass-to-charge ratio (m/z) of the selected precursor ion?
608
Caption: Figure 1: Determination of the MPIase structure. Description: (b, top) MALDI–TOF MS spectrum of MPIase in the negative mode. Subdivided peaks differing in 42 mass units reflect variation ofO-acetyl groups. (Bottom) The MS/MS spectrum fromm/z608 in the positive mode contained fragment peaks comprising combinati...
0
3,315
In the mass spectrum above, what is the mass-to-charge ratio (m/z) of the signal peak with the highest intensity (Intens.)?
5614
Caption: Figure 1: Determination of the MPIase structure. Description: (b, top) MALDI–TOF MS spectrum of MPIase in the negative mode. Subdivided peaks differing in 42 mass units reflect variation ofO-acetyl groups. (Bottom) The MS/MS spectrum fromm/z608 in the positive mode contained fragment peaks comprising combinati...
0
3,316
At approximately which wavelength is the characteristic peak marked by the vertical dashed line located?
approximately 275 nm
Caption: Fig. 2: Two representative recent studies from other research groups that directly support our conclusions. Description: c. In-situ UV-vis study of CuPc under electrochemical CO2 reduction conditions. Adapted with permission from Ref.5.
0
3,317
Among the three spectra at the bottom, which one exhibits the lowest absorbance at 400 nm?
Pc
Caption: Fig. 2: Two representative recent studies from other research groups that directly support our conclusions. Description: c. In-situ UV-vis study of CuPc under electrochemical CO2 reduction conditions. Adapted with permission from Ref.5.
0
3,318
As the applied voltage was varied from –0.54 V to –1.14 V, how did the intensity of the absorption peak at approximately 325 nm change?
gradually decreases
Caption: Fig. 2: Two representative recent studies from other research groups that directly support our conclusions. Description: c. In-situ UV-vis study of CuPc under electrochemical CO2 reduction conditions. Adapted with permission from Ref.5.
1
3,319
How many spectral curves measured under specific negative voltage conditions are displayed in the figure?
7
Caption: Fig. 2: Two representative recent studies from other research groups that directly support our conclusions. Description: c. In-situ UV-vis study of CuPc under electrochemical CO2 reduction conditions. Adapted with permission from Ref.5.
1
3,320
What is the absorbance (Abs) value represented by the scale bar?
0.2 Abs
Caption: Fig. 2: Two representative recent studies from other research groups that directly support our conclusions. Description: c. In-situ UV-vis study of CuPc under electrochemical CO2 reduction conditions. Adapted with permission from Ref.5.
0
3,321
In the illustration, what is the Miller index of the diffraction peak marked by the dashed line?
It is 110.
Caption: Figure 1: In-plane chemical ordering of (Mo2/3Sc1/3)2AlC leading to Mo1.33C MXene with ordered divacancies. Description: (e) Rietveld refinement of XRD of sample with nominal composition (Mo2/3Sc1/3)2AlC assuming same space group as above. (f) XRD pattern of (Mo2/3Sc1/3)2AlC before (black), after HF etching ...
0
3,322
Which sample has the maximum d-spacing value at a 2θ angle of approximately 10°?
Mo₁.₃₃C-HF-TBAOH
Caption: Figure 1: In-plane chemical ordering of (Mo2/3Sc1/3)2AlC leading to Mo1.33C MXene with ordered divacancies. Description: (e) Rietveld refinement of XRD of sample with nominal composition (Mo2/3Sc1/3)2AlC assuming same space group as above. (f) XRD pattern of (Mo2/3Sc1/3)2AlC before (black), after HF etching ...
0
3,323
Comparing the four curves in Figure f, which sample exhibits the broadest diffraction peak in the 2θ range of 5° to 15°?
d-Mo₁.₃₃CTₓ, "paper"
Caption: Figure 1: In-plane chemical ordering of (Mo2/3Sc1/3)2AlC leading to Mo1.33C MXene with ordered divacancies. Description: (e) Rietveld refinement of XRD of sample with nominal composition (Mo2/3Sc1/3)2AlC assuming same space group as above. (f) XRD pattern of (Mo2/3Sc1/3)2AlC before (black), after HF etching ...
0
3,324
What is the d-spacing value corresponding to the most intense diffraction peak of the Mo₁.₃₃CTₓ-HF sample?
19.4 Å
Caption: Figure 1: In-plane chemical ordering of (Mo2/3Sc1/3)2AlC leading to Mo1.33C MXene with ordered divacancies. Description: (e) Rietveld refinement of XRD of sample with nominal composition (Mo2/3Sc1/3)2AlC assuming same space group as above. (f) XRD pattern of (Mo2/3Sc1/3)2AlC before (black), after HF etching ...
0
3,325
In the legend of Figure e, how many impurity phases are listed in addition to the primary phase (Mo₂/₃Sc₁/₃)₂AlC?
Three types
Caption: Figure 1: In-plane chemical ordering of (Mo2/3Sc1/3)2AlC leading to Mo1.33C MXene with ordered divacancies. Description: (e) Rietveld refinement of XRD of sample with nominal composition (Mo2/3Sc1/3)2AlC assuming same space group as above. (f) XRD pattern of (Mo2/3Sc1/3)2AlC before (black), after HF etching ...
1
3,331
In Figure a, how many samples’ XPS spectra are presented in total?
11
Caption: Figure 4: XPS analysis of increasingly oxidized graphite. Description: (a) HO and (b) HU method. The increasing level of oxidation of graphite is represented by the loss of C–C character and the introduction of oxygen functionality. HU materials show a higher degree of carboxylic functionality compared to HO c...
1
3,332
For sample GO-HU5, into how many distinct peaks was its C 1s spectrum deconvoluted (fitted)?
three
Caption: Figure 4: XPS analysis of increasingly oxidized graphite. Description: (a) HO and (b) HU method. The increasing level of oxidation of graphite is represented by the loss of C–C character and the introduction of oxygen functionality. HU materials show a higher degree of carboxylic functionality compared to HO c...
1
3,333
How does the shape of the main peak at approximately 284.5 eV evolve from GO-HO1 to GO-HO55?
Gradually broadens and decreases in height.
Caption: Figure 4: XPS analysis of increasingly oxidized graphite. Description: (a) HO and (b) HU method. The increasing level of oxidation of graphite is represented by the loss of C–C character and the introduction of oxygen functionality. HU materials show a higher degree of carboxylic functionality compared to HO c...
1
3,334
Which sample’s spectral line first exhibits a distinct split peak or shoulder near 288 eV?
GO-HO15
Caption: Figure 4: XPS analysis of increasingly oxidized graphite. Description: (a) HO and (b) HU method. The increasing level of oxidation of graphite is represented by the loss of C–C character and the introduction of oxygen functionality. HU materials show a higher degree of carboxylic functionality compared to HO c...
0
3,335
Question: In the GO-HU10 spectrum, which fitted peak—the one with the highest intensity or the one with the lowest intensity—is located at a higher binding energy (B.E.) position? Answer: The fitted peak with the lowest intensity is located at a higher binding energy position.
the peak with the lowest intensity
Caption: Figure 4: XPS analysis of increasingly oxidized graphite. Description: (a) HO and (b) HU method. The increasing level of oxidation of graphite is represented by the loss of C–C character and the introduction of oxygen functionality. HU materials show a higher degree of carboxylic functionality compared to HO c...
1
3,336
In the above experiment, what is the ratio of the enolic form to the keto form?
It is 2.5:1.
Caption: Fig. 5: Mechanistic studies of the reactivity of the cycloisomerization. Description: a. 1H NMR studies of a mixture of1band (R)-CPA.
1
3,337
After the addition of (R)-CPA, does the relative content of the keto isomer increase or decrease?
increased
Caption: Fig. 5: Mechanistic studies of the reactivity of the cycloisomerization. Description: a. 1H NMR studies of a mixture of1band (R)-CPA.
1
3,338
What is the ratio of the number of Ha to Hb?
It is 2:1.
Caption: Fig. 5: Mechanistic studies of the reactivity of the cycloisomerization. Description: a. 1H NMR studies of a mixture of1band (R)-CPA.
1
3,339
In the brown trace, comparing the two signals Ha and Hb, which one has the smaller chemical shift?
Ha
Caption: Fig. 5: Mechanistic studies of the reactivity of the cycloisomerization. Description: a. 1H NMR studies of a mixture of1band (R)-CPA.
1
3,340
Which of the two Ha signals in the figure—in the brown line or the cyan line—exhibits the simpler splitting pattern?
Cyan line
Caption: Fig. 5: Mechanistic studies of the reactivity of the cycloisomerization. Description: a. 1H NMR studies of a mixture of1band (R)-CPA.
1
3,351
In all subpanels, which two sub-peaks constitute the G band?
G− and G+
Caption: Figure 2: Raman spectroscopy of t(m+n)LG. Description: Stokes/anti-Stokes Raman spectra in the C peak region and Stokes spectra in the G and 2D spectral regions for four t(m+n)LGs. For comparison, the 2D peaks in SLG and Bernal-stacked BLG are plotted using dotted lines. The fits show that the G band of each t...
0
3,352
In the second spectrum, which of the two peaks, C₃₁ or C₃₂, has the greater intensity?
C₃₁
Caption: Figure 2: Raman spectroscopy of t(m+n)LG. Description: Stokes/anti-Stokes Raman spectra in the C peak region and Stokes spectra in the G and 2D spectral regions for four t(m+n)LGs. For comparison, the 2D peaks in SLG and Bernal-stacked BLG are plotted using dotted lines. The fits show that the G band of each t...
1
3,353
In the negative Raman shift region, which spectrum’s signal intensity has been amplified by the greatest factor?
Green and violet spectra
Caption: Figure 2: Raman spectroscopy of t(m+n)LG. Description: Stokes/anti-Stokes Raman spectra in the C peak region and Stokes spectra in the G and 2D spectral regions for four t(m+n)LGs. For comparison, the 2D peaks in SLG and Bernal-stacked BLG are plotted using dotted lines. The fits show that the G band of each t...
0
3,354
How many distinct t(m+n)LG spectral curves are presented in this composite figure?
Four lines
Caption: Figure 2: Raman spectroscopy of t(m+n)LG. Description: Stokes/anti-Stokes Raman spectra in the C peak region and Stokes spectra in the G and 2D spectral regions for four t(m+n)LGs. For comparison, the 2D peaks in SLG and Bernal-stacked BLG are plotted using dotted lines. The fits show that the G band of each t...
1
3,355
In which colored spectrum does the characteristic peak labeled C₂₁ exhibit the lowest intensity?
The topmost is cyan-blue.
Caption: Figure 2: Raman spectroscopy of t(m+n)LG. Description: Stokes/anti-Stokes Raman spectra in the C peak region and Stokes spectra in the G and 2D spectral regions for four t(m+n)LGs. For comparison, the 2D peaks in SLG and Bernal-stacked BLG are plotted using dotted lines. The fits show that the G band of each t...
0
3,356
In the spectrum, among the two signal peaks with chemical shifts between 20 and 25 ppm, which one exhibits the higher intensity?
Signal peak at approximately 23.5 ppm
Caption: Fig. 5 Description: The methyl group carbon C25 arises from C2 of acetate. Comparison of13C NMR spectra for2isolated after growth in the presence of [1,2-13C2] sodium acetate. Integration of the13C NMR spectra confirmed weak enrichment of the13C isotope and the absence of coupling to any adjacent carbon atom. ...
1
3,357
Which two carbon atoms correspond to the 44.58 Hz coupling constant?
C1 and C24
Caption: Fig. 5 Description: The methyl group carbon C25 arises from C2 of acetate. Comparison of13C NMR spectra for2isolated after growth in the presence of [1,2-13C2] sodium acetate. Integration of the13C NMR spectra confirmed weak enrichment of the13C isotope and the absence of coupling to any adjacent carbon atom. ...
0
3,358
What is the peak shape of the C24 signal in the above spectrum?
triplet peak
Caption: Fig. 5 Description: The methyl group carbon C25 arises from C2 of acetate. Comparison of13C NMR spectra for2isolated after growth in the presence of [1,2-13C2] sodium acetate. Integration of the13C NMR spectra confirmed weak enrichment of the13C isotope and the absence of coupling to any adjacent carbon atom. ...
0
3,359
At approximately which chemical shift value (ppm) does the break in the horizontal axis occur?
Between 27 ppm and 138 ppm
Caption: Fig. 5 Description: The methyl group carbon C25 arises from C2 of acetate. Comparison of13C NMR spectra for2isolated after growth in the presence of [1,2-13C2] sodium acetate. Integration of the13C NMR spectra confirmed weak enrichment of the13C isotope and the absence of coupling to any adjacent carbon atom. ...
0
3,360
In the cyan spectrum, are the splitting patterns of the C1 and C24 signals identical?
Yes
Caption: Fig. 5 Description: The methyl group carbon C25 arises from C2 of acetate. Comparison of13C NMR spectra for2isolated after growth in the presence of [1,2-13C2] sodium acetate. Integration of the13C NMR spectra confirmed weak enrichment of the13C isotope and the absence of coupling to any adjacent carbon atom. ...
1
3,361
In subfigure a, at approximately which wavelength is the maximum absorption peak (λmax) of the blue curve located?
Approximately 470 nm
Caption: Fig. 8 Description: Reflective UV-VIS spectroscopy on UHMW-PE and LD-PE.aThe Kubelka–Munk, normalized at max. reflection, for non-treated (untreated material), PDC without the plasma treatment step (PDC without plasma), and a PDC-treated (PDC) sample of fibrous UHMW-PE/DR1-A, performed under following PDC cond...
0
3,362
In subfigure b, what is the approximate maximum absorption intensity (Kubelka–Munk value) of the PDC curve?
approximately 0.26
Caption: Fig. 8 Description: Reflective UV-VIS spectroscopy on UHMW-PE and LD-PE.aThe Kubelka–Munk, normalized at max. reflection, for non-treated (untreated material), PDC without the plasma treatment step (PDC without plasma), and a PDC-treated (PDC) sample of fibrous UHMW-PE/DR1-A, performed under following PDC cond...
0
3,363
For the “PDC without plasma” sample, on which substrate material is its absorption stronger in the 400–500 nm range?
UHMW-PE
Caption: Fig. 8 Description: Reflective UV-VIS spectroscopy on UHMW-PE and LD-PE.aThe Kubelka–Munk, normalized at max. reflection, for non-treated (untreated material), PDC without the plasma treatment step (PDC without plasma), and a PDC-treated (PDC) sample of fibrous UHMW-PE/DR1-A, performed under following PDC cond...
1
3,364
In Figure b, beyond approximately which wavelength (nm) do the absorption values of all three materials approach zero?
650 nm
Caption: Fig. 8 Description: Reflective UV-VIS spectroscopy on UHMW-PE and LD-PE.aThe Kubelka–Munk, normalized at max. reflection, for non-treated (untreated material), PDC without the plasma treatment step (PDC without plasma), and a PDC-treated (PDC) sample of fibrous UHMW-PE/DR1-A, performed under following PDC cond...
0
3,365
What substrate material is represented in Figure b?
LD-PE/DR1-A
Caption: Fig. 8 Description: Reflective UV-VIS spectroscopy on UHMW-PE and LD-PE.aThe Kubelka–Munk, normalized at max. reflection, for non-treated (untreated material), PDC without the plasma treatment step (PDC without plasma), and a PDC-treated (PDC) sample of fibrous UHMW-PE/DR1-A, performed under following PDC cond...
0
3,366
Which substance is responsible for the diffraction peak observed between diffraction angles of 45° and 50° in the bottommost sample?
Si
Caption: Fig. 4: Influence of lithiation on chemical composition of nanowires. Description: c. X-ray diffractograms for pSiNs and LipSiNs showing peaks associated with crystalline Si, lithium silicates and amorphous phases within LipSiNs.
0
3,367
Comparing the orange and blue spectra, which sample exhibits a higher degree of crystallinity (provide the chemical formula)?
LipSi-4%
Caption: Fig. 4: Influence of lithiation on chemical composition of nanowires. Description: c. X-ray diffractograms for pSiNs and LipSiNs showing peaks associated with crystalline Si, lithium silicates and amorphous phases within LipSiNs.
1
3,368
How many Si peaks are indicated by the vertical dashed lines?
3
Caption: Fig. 4: Influence of lithiation on chemical composition of nanowires. Description: c. X-ray diffractograms for pSiNs and LipSiNs showing peaks associated with crystalline Si, lithium silicates and amorphous phases within LipSiNs.
1
3,369
Question: In the XRD pattern of LipSi-40%, the diffraction peak at approximately 33° is attributed to which phase? (Provide the chemical formula.)
Li₂Si₂O3
Caption: Fig. 4: Influence of lithiation on chemical composition of nanowires. Description: c. X-ray diffractograms for pSiNs and LipSiNs showing peaks associated with crystalline Si, lithium silicates and amorphous phases within LipSiNs.
0
3,370
In which sample’s diffraction pattern does the most pronounced “amorphous hump” appear?
LipSi-1.3%
Caption: Fig. 4: Influence of lithiation on chemical composition of nanowires. Description: c. X-ray diffractograms for pSiNs and LipSiNs showing peaks associated with crystalline Si, lithium silicates and amorphous phases within LipSiNs.
0
3,376
What is the approximate intensity ratio of the signal peaks at m/z 328 and m/z 330?
approximately 1:1
Caption: Fig. 3: Photoionization mass spectra. Description: Comparison of mass spectra taken at a photon energy of 9.00 eV.aBromocorannulene (C20H9Br) – helium (He) system;bbromocorannulene (C20H9Br) – vinylacetylene (C4H4) system at a reactor temperature of 1200 ± 100 K. The mass peaks of the newly formed C24H12(m/z= ...
1
3,377
In subfigure b, among the cluster of peaks in the m/z 249–251 range, which m/z value corresponds to the most intense peak?
250
Caption: Fig. 3: Photoionization mass spectra. Description: Comparison of mass spectra taken at a photon energy of 9.00 eV.aBromocorannulene (C20H9Br) – helium (He) system;bbromocorannulene (C20H9Br) – vinylacetylene (C4H4) system at a reactor temperature of 1200 ± 100 K. The mass peaks of the newly formed C24H12(m/z= ...
0
3,378
In subfigure b, what are the m/z values of the signal peak marked in red and its isotopic peak, respectively?
300 and 301
Caption: Fig. 3: Photoionization mass spectra. Description: Comparison of mass spectra taken at a photon energy of 9.00 eV.aBromocorannulene (C20H9Br) – helium (He) system;bbromocorannulene (C20H9Br) – vinylacetylene (C4H4) system at a reactor temperature of 1200 ± 100 K. The mass peaks of the newly formed C24H12(m/z= ...
0
3,379
Into how many peaks is the red portion split?
Two
Caption: Fig. 3: Photoionization mass spectra. Description: Comparison of mass spectra taken at a photon energy of 9.00 eV.aBromocorannulene (C20H9Br) – helium (He) system;bbromocorannulene (C20H9Br) – vinylacetylene (C4H4) system at a reactor temperature of 1200 ± 100 K. The mass peaks of the newly formed C24H12(m/z= ...
1
3,380
How many signal peaks in Figure b are explicitly labeled with their m/z values?
eight
Caption: Fig. 3: Photoionization mass spectra. Description: Comparison of mass spectra taken at a photon energy of 9.00 eV.aBromocorannulene (C20H9Br) – helium (He) system;bbromocorannulene (C20H9Br) – vinylacetylene (C4H4) system at a reactor temperature of 1200 ± 100 K. The mass peaks of the newly formed C24H12(m/z= ...
1
3,381
In the emission spectrum of Py1, at approximately which wavelength (nm) does the peak with the highest intensity appear?
Approximately 475 nm
Caption: Fig. 2: Photophysical properties and theoretical calculation of perylene derivatives. Description: a. Normalized UV-vis absorption (abs) and fluorescence emission (em) spectra of Py1-Py4 in toluene.
0
3,382
Question: In the chart below, which compound, Py2 or Py4, exhibits a more red-shifted peak wavelength in its emission spectrum? Answer: Py4 exhibits a more red-shifted emission peak wavelength.
Py2
Caption: Fig. 2: Photophysical properties and theoretical calculation of perylene derivatives. Description: a. Normalized UV-vis absorption (abs) and fluorescence emission (em) spectra of Py1-Py4 in toluene.
1
3,383
In the above figure, do the absorption spectra of Py1 and Py3 essentially overlap in both their shape and spectral position?
Yes
Caption: Fig. 2: Photophysical properties and theoretical calculation of perylene derivatives. Description: a. Normalized UV-vis absorption (abs) and fluorescence emission (em) spectra of Py1-Py4 in toluene.
1
3,384
In the figure below, beyond approximately which wavelength (nm) does the absorption spectrum of Py4 essentially decrease to zero intensity?
Approximately 470 nm
Caption: Fig. 2: Photophysical properties and theoretical calculation of perylene derivatives. Description: a. Normalized UV-vis absorption (abs) and fluorescence emission (em) spectra of Py1-Py4 in toluene.
0
3,385
For the Py2 sample, what is the approximate wavelength difference in nanometers between the longest-wavelength absorption peak in the absorption spectrum and the shortest-wavelength emission peak in the emission spectrum?
approximately 30 nm
Caption: Fig. 2: Photophysical properties and theoretical calculation of perylene derivatives. Description: a. Normalized UV-vis absorption (abs) and fluorescence emission (em) spectra of Py1-Py4 in toluene.
1
3,386
Are the experimental data and the fitted data essentially fully coincident?
Yes
Caption: Figure 4: XRD pattern and crystalline structure. Description: (a) XRD profile of CS-COF (red curve), the Pawley-refined pattern (green curve) and their difference (black curve). XRD patterns were simulated using the P1 space group with the 0.8-Å-slipped AA-stacking mode (blue curve).
1
3,387
Compared with the simulated spectrum at the bottom, what characteristics do the peak shapes of the experimental spectrum at the top exhibit?
The peak width is significantly broader.
Caption: Figure 4: XRD pattern and crystalline structure. Description: (a) XRD profile of CS-COF (red curve), the Pawley-refined pattern (green curve) and their difference (black curve). XRD patterns were simulated using the P1 space group with the 0.8-Å-slipped AA-stacking mode (blue curve).
0
3,388
In the top spectrum, what is the Miller index assigned to the weaker diffraction peak located at approximately 25 degrees?
001
Caption: Figure 4: XRD pattern and crystalline structure. Description: (a) XRD profile of CS-COF (red curve), the Pawley-refined pattern (green curve) and their difference (black curve). XRD patterns were simulated using the P1 space group with the 0.8-Å-slipped AA-stacking mode (blue curve).
0
3,389
How many distinct spectral regions does subfigure a contain in the vertical direction?
3
Caption: Figure 4: XRD pattern and crystalline structure. Description: (a) XRD profile of CS-COF (red curve), the Pawley-refined pattern (green curve) and their difference (black curve). XRD patterns were simulated using the P1 space group with the 0.8-Å-slipped AA-stacking mode (blue curve).
1
3,390
At approximately which 2θ angles (degrees) do the largest positive peak and the largest negative peak in the black curve occur?
Approximately 5 degrees
Caption: Figure 4: XRD pattern and crystalline structure. Description: (a) XRD profile of CS-COF (red curve), the Pawley-refined pattern (green curve) and their difference (black curve). XRD patterns were simulated using the P1 space group with the 0.8-Å-slipped AA-stacking mode (blue curve).
0
3,391
In subfigure (c), the sharp absorption peak at approximately 3370 cm⁻¹ is assigned to which vibrational mode of NH₃?
ν₃(NH₃)
Caption: Fig. 1: Infrared (IR) spectra of treated and untreated montmorillonite samples with ammonia. Description: In-situ infrared (IR) spectra of (a) commercial montmorillonite, (b) natural montmorillonite, and (c) ammonia (NH3) ice on a silver substrate at 5 K. IR spectra of ammonia deposited on the surface of comme...
0
3,392
Which sample exhibits the sharpest and strongest single-peak absorption at approximately 3300 cm⁻¹?
NH₃-Silver
Caption: Fig. 1: Infrared (IR) spectra of treated and untreated montmorillonite samples with ammonia. Description: In-situ infrared (IR) spectra of (a) commercial montmorillonite, (b) natural montmorillonite, and (c) ammonia (NH3) ice on a silver substrate at 5 K. IR spectra of ammonia deposited on the surface of comme...
0
3,393
In Figure e, is the absorption peak labeled ν₂(NH₄⁺) sharp or broad in shape?
broad
Caption: Fig. 1: Infrared (IR) spectra of treated and untreated montmorillonite samples with ammonia. Description: In-situ infrared (IR) spectra of (a) commercial montmorillonite, (b) natural montmorillonite, and (c) ammonia (NH3) ice on a silver substrate at 5 K. IR spectra of ammonia deposited on the surface of comme...
0
3,394
How many subfigures labeled with letters does the image contain in total?
7
Caption: Fig. 1: Infrared (IR) spectra of treated and untreated montmorillonite samples with ammonia. Description: In-situ infrared (IR) spectra of (a) commercial montmorillonite, (b) natural montmorillonite, and (c) ammonia (NH3) ice on a silver substrate at 5 K. IR spectra of ammonia deposited on the surface of comme...
1
3,395
Question: In all subplots, besides wavenumber, what parameter is shown on the horizontal axis? What is its unit? Answer: Wavelength, with units of micrometers (µm).
Wavelength; µm
Caption: Fig. 1: Infrared (IR) spectra of treated and untreated montmorillonite samples with ammonia. Description: In-situ infrared (IR) spectra of (a) commercial montmorillonite, (b) natural montmorillonite, and (c) ammonia (NH3) ice on a silver substrate at 5 K. IR spectra of ammonia deposited on the surface of comme...
0
3,396
In the IR spectrum, what does the absorption band at 3400 cm⁻¹ represent?
Existence of molecular water
Caption: Fig. 6: FTIR of Type A filament from Beidoushan. Description: b. FTIR spectrum, with enlargement of 2800–3000 cm–1spectral region (inset). Bands at 2960 cm–1, 2920 cm–1, and 2850 cm–1are due to asymmetric aliphatic CH3(end-methyl), asymmetric, and symmetric aliphatic CH2(methylene-chain), respectively10,11. Re...
0
3,397
In the 2800–3000 cm⁻¹ region, what information is reflected by the changes in absorption peak intensity?
It reflects the relative quantities of the –CH3 and –CH2 groups.
Caption: Fig. 6: FTIR of Type A filament from Beidoushan. Description: b. FTIR spectrum, with enlargement of 2800–3000 cm–1spectral region (inset). Bands at 2960 cm–1, 2920 cm–1, and 2850 cm–1are due to asymmetric aliphatic CH3(end-methyl), asymmetric, and symmetric aliphatic CH2(methylene-chain), respectively10,11. Re...
1
3,398
What are the major absorption peaks in the fingerprint region below 1500 cm⁻¹ associated with?
Related to pyrite.
Caption: Fig. 6: FTIR of Type A filament from Beidoushan. Description: b. FTIR spectrum, with enlargement of 2800–3000 cm–1spectral region (inset). Bands at 2960 cm–1, 2920 cm–1, and 2850 cm–1are due to asymmetric aliphatic CH3(end-methyl), asymmetric, and symmetric aliphatic CH2(methylene-chain), respectively10,11. Re...
1
3,399
What is the wave number corresponding to the absorption peak of νₐₛCH₂?
2920 cm⁻¹
Caption: Fig. 6: FTIR of Type A filament from Beidoushan. Description: b. FTIR spectrum, with enlargement of 2800–3000 cm–1spectral region (inset). Bands at 2960 cm–1, 2920 cm–1, and 2850 cm–1are due to asymmetric aliphatic CH3(end-methyl), asymmetric, and symmetric aliphatic CH2(methylene-chain), respectively10,11. Re...
0
3,400
Which of the two absorption peaks, νₐₛCH₃ or νₛCH₂, exhibits the higher absorbance?
νₛCH₂
Caption: Fig. 6: FTIR of Type A filament from Beidoushan. Description: b. FTIR spectrum, with enlargement of 2800–3000 cm–1spectral region (inset). Bands at 2960 cm–1, 2920 cm–1, and 2850 cm–1are due to asymmetric aliphatic CH3(end-methyl), asymmetric, and symmetric aliphatic CH2(methylene-chain), respectively10,11. Re...
1
3,401
At approximately what chemical shift (ppm) does the signal peak corresponding to cyclic phosphatidylglycerol appear?
approximately 18.5 ppm
Caption: Fig. 2: The phosphorylation of glycerol by imidazole phosphate in paste conditions. Description: b. Representative31P-NMR spectra over time for the reaction of 0.13 mmol calcium imidazole phosphate and 0.65 mmol glycerol in paste conditions at 50 °C. The paste was prepared by leaving 2.0 mL of a 65 mM calcium...
0
3,402
As the time increases from 23 hours to 167 hours, how does the signal peak intensity at approximately –6.1 ppm change?
Increase in intensity
Caption: Fig. 2: The phosphorylation of glycerol by imidazole phosphate in paste conditions. Description: b. Representative31P-NMR spectra over time for the reaction of 0.13 mmol calcium imidazole phosphate and 0.65 mmol glycerol in paste conditions at 50 °C. The paste was prepared by leaving 2.0 mL of a 65 mM calcium...
1
3,403
In the spectrum at t = 167 h, comparing the two signal peaks at approximately 3.9 ppm and 2.5 ppm, which one exhibits the lower intensity?
At approximately 2.5 ppm
Caption: Fig. 2: The phosphorylation of glycerol by imidazole phosphate in paste conditions. Description: b. Representative31P-NMR spectra over time for the reaction of 0.13 mmol calcium imidazole phosphate and 0.65 mmol glycerol in paste conditions at 50 °C. The paste was prepared by leaving 2.0 mL of a 65 mM calcium...
1
3,404
How many fracture points are shown in total on the x-axis of this figure?
2
Caption: Fig. 2: The phosphorylation of glycerol by imidazole phosphate in paste conditions. Description: b. Representative31P-NMR spectra over time for the reaction of 0.13 mmol calcium imidazole phosphate and 0.65 mmol glycerol in paste conditions at 50 °C. The paste was prepared by leaving 2.0 mL of a 65 mM calcium...
1
3,405
In the spectrum at t = 0 h, which five-membered heterocycle is present in the molecular structure corresponding to the signal peak?
Imidazole ring
Caption: Fig. 2: The phosphorylation of glycerol by imidazole phosphate in paste conditions. Description: b. Representative31P-NMR spectra over time for the reaction of 0.13 mmol calcium imidazole phosphate and 0.65 mmol glycerol in paste conditions at 50 °C. The paste was prepared by leaving 2.0 mL of a 65 mM calcium...
0